PhD thesis (M/F) in homogeneous catalysis
New
- FTC PhD student / Offer for thesis
- 36 months
- BAC+5
This offer is available in English version
This offer is open to people with a document recognizing their status as a disabled worker.
Offer at a glance
The Unit
Institut des sciences chimiques de Rennes
Contract Type
FTC PhD student / Offer for thesis
Working hHours
Full Time
Workplace
35042 RENNES
Contract Duration
36 months
Date of Hire
01/12/2026
Remuneration
2300 € gross monthly
Apply Application Deadline : 20 October 2026 23:59
Job Description
Thesis Subject
The objective of the thesis is to develop catalytic enantioselective and stereoconvergent allylic C-H functionalization from (E)/(Z)-alkene mixtures. Our catalytic system would enable isomer mixtures to converge to a single enantiopure compound, therefore designing sustainable synthetic sequences of high-value chemicals. A strategy based on dual iron/photoredox catalysis will be developed. An approach combining organometallic synthesis of iron complexes and mechanism investigations leading to application in enantioselective catalysis will be implemented. Characterization techniques such as NMR, Mössbauer, UV-Vis spectroscopies, chromatography (GC, HPLC), X-ray diffraction, fluorometry and cyclic voltammetry will be used. The outcome of this study will provide a light-promoted sustainable access to high-value enantiopure molecules from isomeric mixtures, and advance the field of iron catalysis, an abundant and non-toxic transition metal.
The candidate will be involved into the following tasks:
- Synthesis of sensitive organometallic iron catalysts (inert atmosphere, glovebox technique);
- Mechanism investigations (stoichiometric studies, isolation of key intermediates, ground-state photophysic studies, DFT calculations);
- Optimization of enantioselective dual iron/photoredox catalysis and scope investigation.
Profile: The candidate will hold a M2 degree or equivalent in molecular chemistry. A previous experience in organic synthesis, homogenous (photo)catalysis or/and in organometallic synthesis is required to apply. Previous experience with Schlenk techniques and gloveboxes will be appreciated. Enthusiasm, autonomy, scientific curiosity and ability to communicate in English are required qualities.
Your Work Environment
The successful candidate will be assigned to the Organometallic Sustainable Catalysis group within the OMC team at UMR 6226. They will work in a group comprising 8 researchers and faculty members, 2 research assistants, about 10 doctoral students, and, depending on the time of year, up to 15 interns.
Constraints and risks
Wearing individual protective equipments for chemicals, working under a fume hood, working in a glove box.
Compensation and benefits
Compensation
2300 € gross monthly
Annual leave and RTT
44 jours
Remote Working practice and compensation
Pratique et indemnisation du TT
Transport
Prise en charge à 75% du coût et forfait mobilité durable jusqu’à 300€
About the offer
| Offer reference | UMR6226-CORDUC-003 |
|---|---|
| CN Section(s) / Research Area | Coordination chemistry, catalysis, interfaces, and processes |
About the CNRS
The CNRS is a major player in fundamental research on a global scale. The CNRS is the only French organization active in all scientific fields. Its unique position as a multi-specialist allows it to bring together different disciplines to address the most important challenges of the contemporary world, in connection with the actors of change.
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