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Reference : UMR5069-SAMLAK-003
Workplace : TOULOUSE
Date of publication : Monday, April 26, 2021
Scientific Responsible name : Sami Lakhdar
Type of Contract : PhD Student contract / Thesis offer
Contract Period : 36 months
Start date of the thesis : 4 October 2021
Proportion of work : Full time
Remuneration : 2 135,00 € gross monthly
Description of the thesis topic
The present project aims at understanding the ambident reactivity of (PCO–) by studying kinetics its reactivity with a large variety of electrophiles. This will allow distinguishing between the oxygen and the phosphorus reactivity. Based on this study a rational design of new reactions, especially in the field of organocatalysis, can be envisioned.
The second part of this thesis concern the use of (PCO–) in photoredox catalysis, where access to original organophosphorus molecules is planned. Mechanistic studies of these processes will be investigated by using laser flash photolysis and fluorescence spectroscopy.
The LHFA is a joint CNRS-UPS research unit located in the UPS chemistry building, 118 route de Narbonne, Toulouse. The laboratory is made up of 6 research teams and includes around sixty people. Its core activity is the synthesis and study of original molecules, highly reactive species.
Constraints and risks
Nothing to mention.
Nothing to mention-
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